Polarization is a key process in the fabrication of piezoelectric semiconductor materials, which directly affects their piezoelectric properties. According to the method of interlayer polarization, a multi-polarization experimental device was developed to solve the polarization problem of piezoelectric semiconductors. The performance of GaN after polarization is systematically studied. It is found that the polarization makes GaN materials have piezoelectric properties to affect their mechanical and electrical properties. Polarization significantly improves the conductivity of piezoelectric semiconductors and changes the bending strength.