The effects of interlayer on color purity were studied by inserting different thickness of TmPyPb into the interface between blue and green emissions based on the structure of ITO/NPB/TCTA/Ir(MDQ)2(acac)∶TCTA/TCTA/FIrpic∶TmPyPb/Ir(ppy)3∶TmPyPb/TmPyPb/LiF/Al. The results show that the distribution of exciton and energy transfer can be adjusted and influenced by the thickness of interlayer. WOLED with peak efficiency of 11.58cd/A and CIE coordinates of (0.33,0.36) can be obtained when the thickness is 4nm.