High quality epitaxial material is the precondition of high performance semiconductor optoelectronic devices. With the test of PL photoluminescence system, it is found that both the intensity and uniformity are affected by Ⅴ/Ⅲ ratio after making the characterization of a convenient quantum well structure. With the standard deviation statistic algorithm, it is concluded that luminous intensity comes to be the highest when the Ⅴ/Ⅲ ratio is 35 during the growth of quantum wells. Based on the optimization of process parameters, high-power 980nm laser diodes have been fabricated. For the uncoated devices, the average output power and central wavelength is 9.6W and 977.2nm respectively at a 15A pulsed current.