Abstract:A set of environment stability real-time self-calibration algorithm procedure for PSIM is presented, combining digital signal processing of FFT, filtering and IFFT etc., to resolve the problem of PSIM environment stability. The algorithm is set based on strict theoretical derivation and earlier research on the mechanism of how the PSIM modulates and demodulates the spectropolarizaton information. The demodulation coefficient of PSIM can be self-calibrated, as its variation introduced by environmental disturbance can be isolated from the measured data of PSIM system by the algorithm procedure, and so the environment adaptability of the PSIM can be enhanced effectively too.