The electrical properties of dislocations in n-type 4H-SiC material were studied by Raman scattering techniques at room temperature. The results show that the electron concentration of both the threading screw dislocation (TSD) and the threading edge dislocations (TED) are higher than that of the dislocation-free zone, and the electron concentration TSD is higher than that of TED. Based on the dislocation theory, the relationship between the electron distribution and dislocation structure was discussed. It is suggested that the unsaturated Si bond in TED and increasing electronegativity of Si atom in TSD make dislocations electron concentration are higher than that in the dislocation-free zone.