Investigated was the technology for fabricating single mode optical channel waveguide on X-cut LiNbO3 substrate by using non-toxic and non-corrosive stearic acid melts. The technical conditions for realizing such an optical channel waveguide were obtained by investigating exchange conditions and annealing properties of a planar waveguide. And the waveguides along Y direction with different channel width were fabricated on X-cut LiNbO3 substrate. The measurement results show that the propagation loss less than 1dB/cm is realized for the single mode waveguide with the width of 6μm.