Abstract:In order to study the photoelectric characteristics of increasing the electron injection, white organic light-emitting diodes with the structure of ITO/NPB/Rubrene/NPB/DPVBi/Alq3/LiF/Al were fabricated. Four devices with different inserting layer were fabricated as: for the first one, there is no insert of photoelectric material CdS; for the second one, CdS layer is inserted between NPB and ITO; for the third one, it is inserted between Alq3and LiF and for the fourth one, it is inserted both of them. From the current density-voltage characteristics, it is noticed that the current density of WOLEDs is higher than the others through inserting CdS between Alq3 and LiF under the same condition. Only the current density of the second device increases. The reason is that the CdS thin layer absorbs part of the short wavelength blue-light emission and increases the electron injection of the device, and also the number and ratio of excitions increase correspondingly, so the brightness and efficiency of the device are improved.