Abstract:In this article, a n-type conductance ZnO thin film was deposited on p-Si film by magnetron sputtering Al-doped ZnO ceramic target, and then ZnO/p-Si heterojunctions were preparated. The photoelectric properties, carrier transport properties and conductive mechanism were studied by testing the I-V and C-V characteristics with and without illumination. The results show that ZnO/p Si heterojunctions obtain good rectifying properties and photoelectric response, and can be widely used in photoelectric detection and solar cells. As the conduction band and valence band offset in the ZnO/p-Si heterojunction is too big, the current transport mechanism is dominated by the space charge limited current (SCLC) conduction when the forward voltage exceeds 1V. And it is also suggested the existence of a large number of interface state in ZnO/p-Si heterojunction, and the photoelectric properties can be further improved by reducing interface states.