Abstract:The influence of Al interlayer on the growth of AlN on Si(111) substrate was studied by using PA-MBE. It is found that the AlN crystalline quality is improved by introducing the Al interlayer, and the holes on epitaxial surface can be eliminated by adopting a pre-diffusing process. Futhermore, the AlN grown with pre-diffusing Al interlayer proves to be Al-polar, otherwise presenting N-polar characteristics.