Fluoride-based plasma treatment was used prior to the Schottky evaporation on the undoped Al0.45Ga0.55N, in which the Al content corresponded to the solar-blind wavelength. Compared with the sample without F-treatment, the reverse leakage current density at -10V ofAl0.45Ga0.55N Schottky diodes decreased with increasing treatment time. The leakage current density of the sample with F-treatment for 1min was reduced by 5 orders of magnitude. The formation of Ga-F bond and Al-F bond after treatment was confirmed by X-ray photoemission spectroscopy (XPS). The reduction of leakage current was attributed to the depletion of electron and the passivation of surface states by fluoride-based plasma treatment.